Thanks to Howitworks for this:
Swords were the first tools designed solely to kill. There were other weapons before swords, such as spears, axes and knives, but they were all originally intended for other purposes before being adopted as instruments of war. The spear was originally made for hunting, the axe for chopping wood, while knives have many functions. But the sword exists only to kill people.
Initially, swords were as much status items as weapons. These first swords, appearing from around 3000 BCE, were forged from bronze, an alloy of copper and tin. As the technology required to forge bronze was still new, and bronze itself quite rare, these early swords were very uncommon, highly prized and a sign that the person carrying them was extraordinarily wealthy and powerful. One such example is the bronze sword, shaped like a sickle, that was buried with Tutankhamun circa 1327 BCE. Called a khopesh, the sword of the pharaoh was sharpened on its outside edge, with the tip used both as a hook and a club.
The technology to make bronze spread around the Mediterranean basin, and trade evolved to bring tin from mines in the Iberian Peninsula and Cornwall to the forges of the eastern Mediterranean. As a result, swords became more and more widespread, until whole armies carried them. The Minoan, Sumerian and Assyrian empires were all carved out by armies carrying bronze swords. But iron changed everything. The metal itself is common, strong and durable, and will produce a weapon that is both flexible and tough. The Hittites were early adopters of this technology, using iron weapons to form their empire from 1600 BCE onwards. With the Hittites showing the way, iron became the new material from which to forge swords.